程瑞华，工学博士，副教授，硕士生导师。

E-mail：rhcheng@gdut.edu.cn

教育经历：

中国科学院大连化学物理研究所，2000.9-2006.12

工业催化专业，工学博士（硕博连读），导师：张涛研究员、院士

内蒙古大学，1996.9-2000.7

化学基地专业，理学学士，赵薇副教授

工作经历：

广东工业大学生物医药学院制药工程系，副教授，2021.10-至今

华东理工大学化学化工学院化学工程系，讲师，副教授，2007.9-2021.9

美国加州大学伯克利分校生物与化学工程学院Jeffrey A. Reimer教授课题组，访问学者，2013.9-2015.1

研究方向：

从事药物合成、高分子合成、催化剂开发及工艺开发研究。目前主要研究方向有：

（1）原料药及中间体合成用（手性）催化剂开发及催化机理研究，药物连续流动合成技术与工程。

（2）生物药用高分子材料，包括药用辅料、可降解药物传输/释放控制载体、抗菌水凝胶、刺激响应水凝胶、杀菌医用敷料的设计、合成与性能研究。

（3）二氧化碳的高效转化和利用，聚（氨）酯的催化合成。

（4）新型烯烃聚合/齐聚催化体系的开发、机理研究及应用；高性能聚烯烃产品，尼龙12单体、聚异丁烯等开发与应用。

主要科研项目：

主持和作为技术骨干参加了多项国家、省部级课题的研究工作。负责上海市浦江人才项目1项；国家自然科学青年基金1项；2013、2010年度中央高校基本科研业务费专项资金2项；中石油研究院横向项目2项；万华化学公司横向项目多项。其中承担的“丁二烯三聚环合成环十二碳”单体项目，已在万华化学率先实现了高性能尼龙-12的国产化，打破了以赢创为代表的海外公司在高端长链尼龙领域的垄断。同时作为主要完成人参与多项国家、省部级及国内外企业横向项目。

论文发表：

1. Zhang, H.; Liu, Y.; Zhang, L.; Wang, X.; Sun, H.; Liu, C.; Ye, J.; Cheng, R., Direct reductive amination from ketones, aldehydes to synthesize amines using N, S-dual doped Co/C catalyst. Catal. Lett. 2022, doi: 10.1007/s10562-021-03911-2.

2. Wang, J.; Liu, C.; Cao, L.; Xiong, Y.; Ye, J.; Liu, Z.; Cheng, R., Theoretical investigation of mechanism and ligand effects on half-sandwich iridium complexes for direct reductive amination. Mol. Catal. 2022, 517, 112050.

3. Zou, C.; Yang, L.; Zhang, L.; Liu, C.; Ma, Y.; Song, G.; Liu, Z.; Cheng, R.; Ye, J., Enantioselective vinylogous conia-ene reaction catalyzed by a disilver(i)/bisdiamine complex. ACS Catal. 2021, 11 (12), 6865-6871.

4. Sun, M.; Yang, J.; Fu, Y.; Liang, C.; Li, H.; Yan, G.; Yin, C.; Yu, W.; Ma, Y.; Cheng, R.; Ye, J., Continuous flow process for the synthesis of betahistine via aza-Michael-type reaction in water. Org. Process Res. Dev. 2021, 25 (5), 1160-1166.

5. Sun, M.; Liang, C.; Shen, X.; Li, J.; Cheng, R.; Ye, J., Continuous flow science in an undergraduate teaching laboratory: synthesis of ethylene glycol diacetate using heterogeneous catalysts in continuous flow. J. Chem. Educ. 2021, 98 (2), 572-576.

6. Sun, M.; Li, J.; Liang, C.; Shan, C.; Shen, X.; Cheng, R.; Ma, Y.; Ye, J., Practical and rapid construction of 2-pyridyl ketone library in continuous flow. J. Flow Chem. 2021, 11 (2), 91-98.

7. Ma, Y.; Hong, J.; Yao, X.; Liu, C.; Zhang, L.; Fu, Y.; Sun, M.; Cheng, R.; Li, Z.; Ye, J., Aminomethylation of aryl bromides by nickel-catalyzed electrochemical redox neutral cross coupling. Org. Lett. 2021, 23 (24), 9387-9392.

8. Liu, L.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Ligand-induced product switching between 4-methyl-1-pentene and 2-methyl-1-pentene in bis(imino)pyridine/v(iii)-catalyzed propylene dimerization: cossee-arlman versus metallacycle mechanism. Organometallics 2021, 40 (11), 1682-1691.

9. Liu, K.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Mechanistic studies of reduction and initiation over the vanadium-oxide polyethylene catalyst. J. Phys. Chem. C 2021, 125 (4), 2393-2402.

10. Liu, K.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Mechanistic study of vanadium-modified and sulfation-modified Phillips catalyst. Mol. Catal. 2021, 513, 111777.

11. Liang, C.; Sun, M.; Shen, X.; Shan, C.; Wang, W.; Cheng, R.; Ye, J., Three-step one-pot process of 3-methyl-5-benzofuranol from amine, aldehydes, and p-benzoquinone. Org. Process Res. Dev. 2021, 25 (4), 810-816.

12. Feng, Z.; Wu, L.; Dong, H.; Liu, B.; Cheng, R., Copolyesters of ε-caprolactone and L-lactide catalyzed by a tetrabutylammonium phthalimide-N-oxyl organocatalyst. RSC Adv. 2021, 11 (31), 19021-19028.

13. Wu, L.; Liu, W.; Ye, J.; Cheng, R., Fast cyclotrimerization of a wide range of isocyanates to isocyanurates over acid/base conjugates under bulk conditions. Catal. Commun. 2020, 145, 106097.

14. Tong, Y.; Cheng, R.; Yu, L.; Liu, B., New strategies for synthesis of amino-functionalized poly(propylene carbonate) over SalenCo(III)Cl catalyst. J. Polym. Sci. 2020, 58 (9), 1325-1337.

15. Liu, Y.; Zhang, R.; Ren, H.; Liu, Y.; Ling, S.; Zhang, H.; Liu, B.; Cheng, R., CrV bimetallic Phillips catalyst prepared by citric acid-assisted impregnation on ethylene polymerization. Macromol. Chem. Phys. 2020, 221 (10), 2000010.

16. Liu, K.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Mechanistic study on the effects of co-catalyst on ethylene polymerization over supported vanadocene catalyst. Mol. Catal. 2020, 486, 110852pp.

17. Ling, S.; Ren, H.; Zhang, R.; Liu, Y.; Liu, B.; Cheng, R., Insights into the effect of vanadium on chromiumvanadium Phillips catalysts for the ethylene polymerization. Polyolefins J. 2020, 7 (2), 61-78.

18. Wu, G.; Wang, J.; Liu, C.; Sun, M.; Zhang, L.; Ma, Y.; Cheng, R.; Ye, J., Transition metal-free, visible-light-mediated construction of α,β-diamino esters via decarboxylative radical addition at room temperature. Org. Chem. Front. 2019, 6 (13), 2245-2249.

19. Ma, Y.; Yao, X.; Zhang, L.; Ni, P.; Cheng, R.; Ye, J., Direct arylation of α-amino C(sp3)-H bonds by convergent paired electrolysis. Angew. Chem., Int. Ed. 2019, 58 (46), 16548-16552.

20. Lu, M.; Li, H.; Zou, C.; Li, J.; Liu, C.; Sun, M.; Ma, Y.; Cheng, R.; Ye, J., Primary amine catalyzed diastereo- and enantioselective Michael reaction of thiazolones and α, β-unsaturated ketones. Org. Biomol. Chem. 2019, 17 (42), 9305-9312.

21. Liu, L.; Liu, Z.; Tang, S.; Cheng, R.; He, X.; Liu, B., What triggered the switching from ethylene-selective trimerization into tetramerization over the Cr/(2, 2'-dipicolylamine) catalysts? ACS Catal. 2019, 9 (11), 10519-10527.

22. Jin, Y.; Liu, B.; Chen, L.; Guo, X.; Xu, L.; Zhu, Z.; Liu, Z.; Cheng, R., A Complexed initiating system AlCl₃·phenetole/TiCl₄·H₂O with dominant synergistic effect for efficient synthesis of high molecular weight polyisobutylene. Polymers 2019, 11 (12), doi: 10.3390/polym11122121.

23. Jin, Y.; Dong, K.; Xu, L.; Guo, X.; Cheng, R.; Liu, B., Facile synthesis of medium molecular weight polyisobutylene with remarkable efficiency employing the complexed BF₃·EtOH/TiCl₄·H₂O initiating system. Eur. Polym. J. 2019, 120, 109204.

24. Jin, Y.; Chen, L.; Guo, X.; Xu, L.; Zhu, Z.; Liu, Z.; Cheng, R.; Liu, B., A complexed initiating system AlCl₃.bul.phenetole/TiCl₄.bul.H₂O with dominant synergistic effect for efficient synthesis of high molecular weight polyisobutylene. Polymers 2019, 11 (12), 2121.

25. Zhu, L.; He, X.; Cheng, R.; Liu, Z.; Zhao, N.; Liu, B., Effects of Ti/Mg molar ratio on bi-supported SiO₂/MgCl₂ (ethoxide type)/TiCl₄ catalysts in ethylene homopolymerization and ethylene/1-hexene copolymerization. Polyolefins J. 2018, 5 (1), 1-13.

26. Liu, L.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Unraveling the effects of H₂, N substituents and secondary ligands on Cr/PNP-catalyzed ethylene selective oligomerization. Organometallics 2018, 37 (21), 3893-3900.

27. Li, Y.; Liu, Z.; Zhang, J.; Cheng, R.; Liu, B., Insights into the base-assisted acrylate formation from CO₂/C₂H₄ coupling by Pd- and Ni-catalyst: a DFT mechanistic study. ChemCatChem 2018, 10 (24), 5669-5678.

28. Li, Y.; Liu, Z.; Cheng, R.; Liu, B., Mechanistic aspects of acrylic acid formation from CO₂-ethylene coupling over palladium- and nickel-based catalysts. ChemCatChem 2018, 10 (6), 1420-1430.

29. Fu, T.; Cheng, R.; He, X.; Liu, Z.; Tian, Z.; Liu, B., How can pH value during catalyst preparation affect the performance of vanadium-modified (SiO₂/MgO/ MgCl₂)·TiCl_x Ziegler-Natta polyethylene catalysts. Polyolefins J. 2018, 5 (1), 31-45.

30.    Cheng, R.; Zhou, Y.; Hou, Q.; Liu, B., ZnO/SiO₂-modified rare-earth-metal ternary catalyst bearing quaternary ammonium salts for synthesis of high molecular weight poly(propylene carbonate). Chin. J. Catal. 2018, 39 (8), 1303-1310.

31. Sun, Q.; Wang, L.; Cheng, R.; Liu, Z.; He, X.; Zhao, N.; Liu, B., A Novel SiO₂-supported fluorine modified chromium-vanadium bimetallic catalyst for ethylene polymerization and ethylene/1-hexene copolymerization. Macromol. React. Eng. 2017, 11 (5), doi: 10.1002/mren.201600055.

32. Sun, Q.; Cheng, R.; Liu, Z.; He, X.; Zhao, N.; Liu, B., Effect of fluoride-modification on the phillips Cr/SiO₂ catalyst for ethylene polymerization. ChemCatChem 2017, 9 (17), 3364-3373.

33. Sun, Q.; Cheng, R.; Liu, Z.; He, X.; Zhao, N.; Liu, B., Introduction of titanium species into fluorine-modified SiO₂-supported Cr-V bimetallic catalyst for ethylene polymerization and ethylene/1-hexene copolymerization. Polyolefins J. 2017, 4 (2), 221-234.

34. Liu, B.; Zhao, N.; Jin, Y.; Cheng, R.; He, X.; Liu, Z.; Liu, B., Effects of alkyl aluminum on sio₂-supported silyl-chromate(Cr)/imido-vanadium(V) bimetallic catalysts for producing bimodal polyethylene. Macromol. React. Eng. 2017, 11 (5), doi: 10.1002/mren.201700006.

35. Jin, Y.; Zhao, N.; Cheng, R.; Liu, B., Research progress of bimetallic catalysts for bimodal polyethylene synthesis. Huagong Xuebao 2017, 68 (2), 485-495.

36. Jin, Y.; Zhao, N.; Cheng, R.; He, X.; Liu, Z.; Liu, B., Remarkable promotion effect of sulfation over the SiO₂-supported vanadium-oxide-based catalysts for UHMWPE. Macromol. Chem. Phys. 2017, 218 (19), doi: 10.1002/macp.201700236.

37. Jin, Y.; Zhao, N.; Cheng, R.; He, X.; Liu, Z.; Dong, D.; Bin, Y.; Chen, X.; Li, L.; Liu, B., One pot synthesis of bimodal UHMWPE/HDPE in-reactor blends with Cr/V bimetallic catalysts. J. Polym. Sci., Part A: Polym. Chem. 2017, 55 (20), 3404-3412.

38. Jin, Y.; Cheng, R.; He, X.; Liu, Z.; Zhao, N.; Liu, B., The first vanadium-oxide-based UHMWPE catalyst supported on chemically modified silica gel. Macromol. Chem. Phys. 2017, 218 (7), doi: 10.1002/macp.201600443.

39. Fu, T.; Liu, Z.; Cheng, R.; He, X.; Tian, Z.; Liu, B., Ethylene polymerization over MgCl₂/SiO₂ Bi-supported Ziegler-Natta hybrid titanium/vanadium catalysts. Macromol. Chem. Phys. 2017, 218 (13), doi: 10.1002/macp.201700027.

40. Cheng, R.; Liu, X.; Fang, Y.; Terano, M.; Liu, B., High-resolution ²⁹Si CP/MAS solid state NMR spectroscopy and DFT investigation on the role of geminal and single silanols in grafting chromium species over Phillips Cr/silica catalyst. Appl. Catal., A 2017, 543, 26-33.

41. Wang, J.; Cheng, R.; He, X.; Liu, Z.; Zhao, N.; Liu, B., Vanadium modification effects on the (SiO₂/MgO/MgCl₂).TiCl_x Ziegler-Natta polyethylene catalyst. Macromol. React. Eng. 2016, 10 (3), 246-260.

42. Meng, Q.; Cheng, R.; Li, J.; Wang, T.; Liu, B., Copolymerization of CO₂ and propylene oxide using ZnGA/DMC composite catalyst for high molecular weight poly(propylene carbonate). J. CO₂ Util. 2016, 16, 86-96.

43. Li, J.; Cheng, R.; Ma, Y.; Liu, B., Imido-modified SiO₂-supported Cr/Mo catalyst for ethylene polymerization. Hecheng Shuzhi Ji Suliao 2016, 33 (1), 16-20.

44. Huang, F.; Wang, J.; Cheng, R.; He, X.; Liu, Z.; Zhao, N.; Liu, B., Optimization of the preparation temperature for the novel (SiO₂/MgO/MgCl₂)·TiCl_x Ziegler-Natta polyethylene catalyst. Macromol. React. Eng. 2016, 10 (6), 567-576.

45. Fu, T.; Cheng, R.; He, X.; Liu, Z.; Tian, Z.; Liu, B., Imido-modified SiO₂-supported Ti/Mg Ziegler-Natta catalysts for ethylene polymerization and ethylene/1-hexene copolymerization. Polyolefins J. 2016, 3 (2), 103-117.

46. Dong, K.; Liu, Z.; Cheng, R.; Liu, B., Synthesis of HR-PIB catalyzed by BF₃-alcohol/ether complexes. Hecheng Shuzhi Ji Suliao 2016, 33 (5), 1-6.

47. Wang, J.; Cheng, R.; He, X.; Liu, Z.; Zhao, N.; Liu, B., Introduction of chromium species into the (SiO₂/MgO/MgCl₂)·TiCl_x Ziegler-Natta catalyst for better catalytic performance. J. Organomet. Chem. 2015, 798, 299-310.

48. Wang, J.; Cheng, R.; He, X.; Liu, Z.; Tian, Z.; Liu, B., A Novel (SiO₂/MgO/MgCl₂)·TiCl_x Ziegler-Natta catalyst for ethylene and ethylene/1-hexene polymerization. Macromol. Chem. Phys. 2015, 216 (13), 1472-1482.

49. Pan, X.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Insight into the reaction mechanisms between CO₂ and epoxides over Zn(II) phenoxide catalytic system - A DFT study. J. Organomet. Chem. 2015, 775, 67-75.

50. Ma, Y.; Wang, L.; Liu, Z.; Cheng, R.; Zhong, L.; Yang, Y.; He, X.; Fang, Y.; Terano, M.; Liu, B., High-resolution XPS and DFT investigations into Al-modified Phillips CrOx/SiO₂ catalysts. J. Mol. Catal. A: Chem. 2015, 401, 1-12.

51. Ma, Y.; Cheng, R.; Li, J.; Zhong, L.; Liu, Z.; He, X.; Liu, B., Effect of Mo-modification over Phillips CrOx/SiO₂ catalyst for ethylene polymerization. J. Organomet. Chem. 2015, 791, 311-321.

52. Ma, Y.; Cheng, R.; Li, J.; Zhong, L.; Liu, Z.; He, X.; Liu, B., Effect of Mo-modification over Phillips CrOx/SiO₂ catalyst for ethylene polymerization. J. Organomet. Chem. 2015, 798, 317-327.

53. Cheng, R.; Xue, X.; Liu, W.; Zhao, N.; He, X.; Liu, Z.; Liu, B., Novel SiO₂-supported chromium oxide(Cr)/vanadium oxide(V) bimetallic catalysts for production of bimodal polyethylene. Macromol. React. Eng. 2015, 9 (5), 462-472.

54. Zhao, N.; Cheng, R.; He, X.; Liu, Z.; Liu, B.; Zhang, R.; Gao, Y.; Zou, E.; Wang, S., Novel SiO₂-supported silyl-chromate(Cr)/imido-vanadium(V) bimetallic catalysts producing polyethylene and ethylene/1-hexene copolymers with bimodal molecular-weight distribution. Macromol. Chem. Phys. 2014, 215 (15), 1434-1445.

55. Zhao, N.; Cheng, R.; He, X.; Liu, Z.; Liu, B., A novel SiO₂-supported Cr-V Bimetallic catalyst making polyethylene and ethylene/1-hexene copolymers with bimodal molecular weight Distribution. Macromol. Chem. Phys. 2014, 215 (18), 1753-1766.

56. Yang, Y.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Mechanistic DFT Study on ethylene trimerization of chromium catalysts supported by a versatile pyrrole ligand system. Organometallics 2014, 33 (10), 2599-2607.

57. Tang, S.; Liu, Z.; Zhan, X.; Cheng, R.; He, X.; Liu, B., 2D-QSPR/DFT studies of aryl-substituted PNP-Cr-based catalyst systems for highly selective ethylene oligomerization. J. Mol. Model. 2014, 20 (3), 1-13.

58. Tang, S.; Liu, Z.; Zhan, X.; Cheng, R.; He, X.; Liu, B., 2D-QSPR studies on substituting PNP-Cr catalyst systems for highly selective ethylene oligomerization. Huagong Xuebao 2014, 65 (1), 131-142.

59. Tang, S.; Liu, Z.; Yan, X.; Li, N.; Cheng, R.; He, X.; Liu, B., Kinetic studies on the pyrrole-Cr-based Chevron-Phillips ethylene trimerization catalyst system. Appl. Catal., A 2014, 481, 39-48.

60. Pan, X.; Liu, Z.; Cheng, R.; Jin, D.; He, X.; Liu, B., Experimental and theoretical studies on CO₂ and propylene oxide (PO) copolymerization catalyzed by ZnEt₂-glycerine-Y(CCl₃COO)₃ ternary catalyst. J. Organomet. Chem. 2014, 753, 63-71.

61. Liu, Z.; He, X.; Cheng, R.; Eisen, M. S.; Terano, M.; Scott, S. L.; Liu, B., Chromium catalysts for ethylene polymerization and oligomerization. Adv. Chem. Eng. 2014, 44 (Catalysis and Kinetics), 127-191.

62. Liu, Z.; Cheng, R.; He, X.; Tian, Z.; Liu, B., Recent progress on molecular modeling of ethylene polymerization/oligomerization catalyzed by chromium-based catalysts. Huaxue Fanying Gongcheng Yu Gongyi 2014, 30 (3), 218-228.

63. Zhong, L.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Effect of fluorination of silica support on initiation of ethylene polymerization during induction period over Phillips catalyst. Huagong Xuebao 2013, 64 (2), 539-546.

64. Zhang, S.; Cheng, R.; Dong, Q.; He, X.; Wang, Q.; Tang, Y.; Yu, Y.; Xie, K.; Da, J.; Terano, M.; Liu, B., Ethylene/1-hexene copolymerization with a novel SiO₂-supported inorganic and organic hybrid chromium-based catalyst. Macromol. React. Eng. 2013, 7 (6), 254-266.

65. Liu, Z.; Cheng, R.; He, X.; Liu, B., Reactivity and regioselectivity of methylacetylene cyclotrimerization over the Phillips Cr/silica catalyst: a DFT study. ACS Catal. 2013, 3 (6), 1172-1183.

66. Li, L.; Wu, Y.; Dong, Q.; Hao, A.; Cheng, R.; Zhong, L.; Liu, B., Effect of Al-alkyl cocatalyst on ethylene polymerization behavior using silyl chromate (SC)/SiO₂ catalyst. Asia-Pac. J. Chem. Eng. 2013, 8 (4), 539-546.

67. Cheng, R.; Liu, Z.; Zhong, L.; He, X.; Qiu, P.; Terano, M.; Eisen, M. S.; Scott, S. L.; Liu, B., Phillips Cr/Silica catalyst for ethylene polymerization. Adv. Polym. Sci. 2013, 257 (Polyolefins: 50 Years after Ziegler and Natta I), 135-202.

68. Zhong, L.; Liu, Z.; Cheng, R.; Tang, S.; Qiu, P.; He, X.; Terano, M.; Liu, B., Active site transformation during the induction period of ethylene polymerization over the Phillips CrOx/SiO₂ catalyst. ChemCatChem 2012, 4 (6), 872-881.

69. Zhang, S.; Zhao, N.; Wu, Y.; Dong, Q.; Wang, Q.; Tang, Y.; Yu, Y.; Da, J.; He, X.; Cheng, R.; Liu, B., Short chain branches distribution characterization of ethylene/1-hexene copolymers by using TREF+¹³C-NMR and TREF+SC methods. Macromol. Symp. 2012, 312, 63-71.

70. Zhang, S.; Dong, Q.; Cheng, R.; He, X.; Wang, Q.; Tang, Y.; Yu, Y.; Xie, K.; Da, J.; Liu, B., A novel SiO2-supported inorganic and organic hybrid chromium-based catalyst for ethylene polymerization. J. Mol. Catal. A: Chem. 2012, 358, 10-22.

71. Qiu, P.; Cheng, R.; Liu, Z.; Liu, B.; Tumanskii, B.; Eisen, M. S., Switching from ethylene polymerization to nonselective oligomerization over a homogeneous model catalyst: A triphenylsiloxy complex of chromium(VI). J. Organomet. Chem. 2012, 699, 48-55.

72. Liu, Z.; Cheng, R.; He, X.; Wu, X.; Liu, B., DFT functional benchmarking on the energy splitting of chromium spin states and mechanistic study of acetylene cyclotrimerization over the Phillips Cr(II)/silica catalyst. J. Phys. Chem. A 2012, 116 (28), 7538-49.

73. Bai, X.; He, X.; Zhang, J.; Zhu, X.; Zhang, H.; Cheng, R.; Liu, B., Improvement of interfacial interaction, dispersion, and properties of chlorosulfonated polyethylene/SiO₂ nanocomposites using CSPE-g-SiO₂ nanoparticles synthesized under ultrasonics. Polym. Compos. 2012, 33 (6), 940-950.

74. Yang, Y.; Liu, Z.; Zhong, L.; Qiu, P.; Dong, Q.; Cheng, R.; Vanderbilt, J.; Liu, B., Spin surface crossing between chromium(I)/sextet and chromium(III)/quartet without deprotonation in SNS-Cr mediated ethylene trimerization. Organometallics 2011, 30 (19), 5297-5302.

75. Qiu, P.; Cheng, R.; Liu, B.; Tumanskii, B.; Batrice, R. J.; Botoshansky, M.; Eisen, M. S., A triphenylsiloxy complex of chromium(II) as a switchable catalyst for ethylene polymerization and nonselective oligomerization. Organometallics 2011, 30 (8), 2144-2148.

76. Liu, Z.; Zhong, L.; Yang, Y.; Cheng, R.; Liu, B., DFT and CASPT2 study on the mechanism of ethylene dimerization over Cr(II)OH⁺ cation. J. Phys. Chem. A 2011, 115 (28), 8131-8141.

77. Wu, Y.; Zhang, H.; Dong, Q.; Yu, Y.; Tang, Y.; Cheng, R.; Liu, B., Ethylene and 1-hexene copolymerization using S-2 Cr-based catalyst. Hecheng Shuzhi Ji Suliao 2010, 27 (2), 1-4.

78. Qi, Y.; Dong, Q.; Zhong, L.; Liu, Z.; Qiu, P.; Cheng, R.; He, X.; Vanderbilt, J.; Liu, B., Role of 1,2-dimethoxyethane in the transformation from ethylene polymerization to trimerization using chromium tris(2-ethylhexanoate)-based catalyst system: a DFT study. Organometallics 2010, 29 (7), 1588-1602.

79. Li, X.; Cheng, R.; Luo, J.; Dong, Q.; He, X.; Li, L.; Yu, Y.; Da, J.; Liu, B., Experimental and theoretical studies on ethylene polymerization using SiO₂-supported silyl chromate type catalysts prepared by a green method. J. Mol. Catal. A: Chem. 2010, 330 (1-2), 56-65.

80. Cao, X.; Cheng, R.; Liu, Z.; Wang, L.; Dong, Q.; He, X.; Liu, B., DFT and PIO study of the influences of Mo valance state and surface hydroxyl on supported-MoOx catalysts for ethylene polymerization. J. Mol. Catal. A: Chem. 2010, 321 (1-2), 50-60.

81. Qiu, P.; Li, X.; Zhang, S.; Cheng, R.; Dong, Q.; Liu, B.; Li, L.; Yu, Y.; Tang, Y.; Xie, J.; Wang, W., Supporting mechanism of non-toxic chromium(III) acetate on silica for preparation of Phillips ethylene polymerization catalysts. Asia-Pac. J. Chem. Eng. 2009, 4 (5), 660-665.

82. Sun, J.; Zheng, M.; Wang, X.; Wang, A.; Cheng, R.; Li, T.; Zhang, T., Catalytic performance of activated carbon supported tungsten carbide for hydrazine decomposition. Catal. Lett. 2008, 123 (1-2), 150-155.

83. Liu, B.; Cheng, R.; Liu, Z.; Qiu, P.; Zhang, S.; Taniike, T.; Terano, M.; Tashino, K.; Fujita, T., Experimental and computational approaches on the isospecific role of monoester-type internal electron donor for TiCl₄/MgCl₂ Ziegler-Natta catalysts. Macromol. Symp. 2007, 260, 42-48.

84. Cheng, R.; Shu, Y.; Zheng, M.; Li, L.; Sun, J.; Wang, X.; Zhang, T., Molybdenum phosphide, a new hydrazine decomposition catalyst: Microcalorimetry and FTIR studies. J. Catal. 2007, 249 (2), 397-400.

85. Cheng, R.; Shu, Y.; Li, L.; Zheng, M.; Wang, X.; Wang, A.; Zhang, T., Synthesis and characterization of high surface area molybdenum phosphide. Appl. Catal., A 2007, 316 (2), 160-168.

86. Zheng, M.; Shu, Y.; Cheng, R.; Zhang, T., Synthesis and characterization of nano iron nitride for application in hydrazine decomposition. Prepr. Symp. - Am. Chem. Soc., Div. Fuel Chem. 2006, 51 (2), 849-850.

87. Zheng, M.; Chen, X.; Cheng, R.; Li, N.; Sun, J.; Wang, X.; Zhang, T., Catalytic decomposition of hydrazine on iron nitride catalysts. Catal. Commun. 2006, 7 (3), 187-191.

88. Cheng, R.; Shu, Y.; Li, L.; Sun, J.; Wang, X.; Zhang, T., CO adsorption on highly dispersed MoP/Al₂O₃ prepared with citric acid. Thermochim. Acta 2006, 450 (1-2), 42-46.

89. Zheng, M.; Cheng, R.; Chen, X.; Li, N.; Li, L.; Wang, X.; Zhang, T., A novel approach for CO-free H₂ production via catalytic decomposition of hydrazine. Int. J. Hydrogen Energy 2005, 30 (10), 1081-1089.

90. Li, L.; Wang, X.; Zhao, X.; Zheng, M.; Cheng, R.; Zhou, L.; Zhang, T., Microcalorimetric studies of the iridium catalyst for hydrazine decomposition reaction. Thermochim. Acta 2005, 434 (1-2), 119-124.

91. Cheng, R.; Li, N.; Zheng, M.; Li, L.; Wang, X.; Zhang, T., Preparation of molybdenum phosphide with high surface area. Cuihua Xuebao 2005, 26 (7), 531-532.

92. Li, N.; Wang, A.; Zheng, M.; Wang, X.; Cheng, R.; Zhang, T., Probing into the catalytic nature of Co/sulfated zirconia for selective reduction of NO with methane. J. Catal. 2004, 225 (2), 307-315.

93. Li, N.; Wang, A.; Wang, X.; Zheng, M.; Cheng, R.; Zhang, T., NO reduction by CH₄ in the presence of excess O₂ over Mn/sulfated zirconia catalysts. Appl. Catal., B 2004, 48 (4), 259-265.